Several possibilities:
- As I read the manual Fn+X+F is this keyboard’s equivalent of Fn lock, maybe try that.
- I believe that AltGr+[ should allow you to type umlauts (at least that works on the GB layout), but I don’t know if that will work on mac mode (I have never used a mac keyboard).
- Alternatively, you could map the compose key to the print screen key (or some other option you wouldn’t mind losing) and then use that (umlauts should be composed using colon+letter, as far as I recall).

Maybe that’s a keyboard layout thing that only works with the UK layout then. If I hit AltGr+[ – maybe I’m misremembering, it could be ] – then e.g. a, (using a UK layout) I get ä.
As a backup, when Fedora updates to Plasma 6.7 (probably with Fedora 45) you’ll have the option of long-pressing keys to get a small alternative letter-popup, which of course still adds a keypress so probably also suboptimal.